About

Providing straightforward information pertaining to drugs, drug use & drug policy. The Grey Pages promotes drug-related literacy and advocates a system of viable and tolerant drug policies. This is my personal collection of commentaries, essays, tid-bits, and other such writings on everything ranging from drug use, drug policy and drug-myths, to drug-science, addiction, human behavior, and the workings of the human brain. I started this blog with a particular focus on opioids, and over the past year have found my interest gravitate toward the intriguing, ever-changing world of designer intoxicants (i.e. "research chemicals" or "designer drugs").

Wednesday, February 15, 2012

Research Chemicals: About

Basics:

"RC's" (or "research chemicals") are quasi legal compounds sold through certain vendors and consumed for their pharmacological effects. They are, more often than not, chemical analogues of popular drugs currently controlled by federal laws. A controlled substance analogue (or CSA) is a compound derived from the same structural family as a certain illicit drug but with one or more molecular modifications, reductions, substitutions, or additions. Research chemicals are popularly known as "designer drugs", or "legal highs", and are sold in a variety of different forms, under a variety of different product names, usually labeled as non-consumable.

Legality:

In the case of our drug laws in the US, only so many certain compounds are listed specifically as controlled substances. The federal analogue act was enacted to address related compounds that are derived from, or structurally similar to, the explicitly listed controlled substances. This law allows for relatively new or obscure drugs that are not yet known, have not yet been outlawed, or have not even been discovered, to be treated as illicit drugs when they are sold and used for such purposes. This essentially allows law enforcement to keep up with the evolving drug market without having to explicitly enact a new law each time a new drug is discovered.

In order to operate within the law, or at least ambiguously within the margins of the law, RC's can not be marketed as drugs and can not be marketed as food. By marketing RC's as a variety of different non-consumable products, research tools, or novelty items, the compounds are able to avoid the regulative scrutiny of food and drug products. Such products contain clear labeling stating "not for human consumption". Such labeling allows the manufacturer and vendor to disclaim liability for potential consumer hazards (for instance, when someone swallows a powder clearly marked "drain cleaner" or "shoe shiner" and becomes ill, it's tough to argue that the manufacturer is liable). But more importantly, such marketing techniques allow the compounds to remain under the public radar and to avoid being conceptualized by law enforcement as controlled substance analogues. For instance, if the compounds were being sold as "tweak pills" or "nose powder" in the same manner that drugs like heroin and cocaine are sold, the authorities can make a strong case that the compounds are being sold and used as street drugs (as opposed to random home or novelty products with active components which just so happen to structurally resemble illicit drugs). And thus due to the context of their sale and use, along with their structural similarities with illicit drugs, can be treated as controlled substance analogues.

Safety:

Before continuing, let me emphasize first and foremost; despite being legal, easily available, and professionally packaged, these compounds are every bit as powerful and every bit as dangerous as any illicit drug. They are mere variants of the same structural families as their illicit alternatives (mutually related to the same extent as oxycodone is to morphine, diazepam is to alprazolam, etc).

As a general rule, their pharmacology exhibits no substantial difference from that of their illicit corellates. They are, generally speaking, every bit as potent and every bit as addictive.

Human consumption of these compounds often entails more risk than use of well established "street" drugs, as the RC products may have little to no history of human use, thus their effects and toxicity profiles are largely unknown. So, there is some potential for a very toxic compound to be marketed and to cause great harm or death to consumers - who basically play the role of consenting human guinea pigs by using some of these compounds.

Common RC's:

Currently there are a variety of available RC's covering a wide range of the psychopharmacological spectrum.  The most popular of the RC's fall into the stimulant, enactogen, and psychedelic/hallucinogen categories. Sedatives and anaesthetics are common as well.

The most prominent RC's are currently members of the following chemical and pharmacological families:

Substituted Phenethylamines, Phenylpropylamines, and Propiophenones (Analogues of amphetamine, methamphetamine, MDMA, cathinone, and pyrovalerone) - This category mainly consists of psychostimulants and enactogens. Some have psychedelic properties as well (2Cx and 2Cx derived compounds).

Tryptamines (Analogues of serotonin, DMT, AMT, and psilocybin)  - This group consists primarily of psychedelics, hallucinogens, or enactogens.

Piperazines (Analogues of benzylpiperazine) - This group consists of mostly psychostimulants and anorectics.

Arylcyclohexylamines/Substituted Arylcyclohexylamines (Analogues of PCP and ketamine) - This catagory consists of dissociative, anaesthetic and sedative agents.

Substituted Indoles/Naphthoylindoles (Analogues of JWH-018 - the original active constituent found in "Spice" products) - This class consists of compounds which are active at cannabinoid receptors and thus mimick the effects of cannabis products (particularly, the active cannabinoids in cannabis; such as THC and CBD)

At this particular moment, following recent bans, a few of the most prominent compounds on the market are as follows (for the sake of protecting the market, I'll use the acronyms, though I'm sure most readers can figure out the identity of the compounds from there):

4-MEC: a cathinone analogue similar to mephedrone with psychostimulant and enactogen properties

4-FA: a halogenated analogue of amphetamine with psychostimulant and enactogen properties

2-FMA: a halogenated analogue of methamphetamine with stimulant and possibly enactogen properties

5-IAI: an aminoindane analogue of MDAI with enactogenic properties

Methoxetamine: an arylcyclohexanamine based dissociative compound closely related to ketamine

a-PVP: an N-pyrrolidinyl derivative of the alkylphenone (substituted cathinone) family. It is an analogue of MDPV and pyrovalerone and produces stimulant effects.

Diphenylprolinol (D2MP): an atypical diphenylpyrrolidine-based stimulant with pharmacology similar to methylphenidate

Ethylphenidate: a phenylpiperidine derived stimulant closely related to methylphenidate

UR-144: an indole derived compound acting at cannabinoid sites

A Lack of Opioid RC's:

There is an exception in terms of RC availability - opioid agonists have been for the most part disregarded by commercial drug chemists. They are not available on the RC market to any significant degree, with the exception of isolated kratom alkaloids and the mild analgesic O-desmethyltramadol.

The rarity of opioids on the RC scene may indeed seem odd without further analysis of the very nature of the RC scene, and the fundamental differences between narcotic drugs and recreational or party drugs. With regard to the former, it seems apparent that the predominant consumers of the RC drugs are recreational users. Often sociable, often young and often naive in terms of drug use & degree of drug experience; such users are often intent on using research chems in a social or thrillseeking context rather than in a maintenance or self-medicating context - accounting for the popularity of the empathenogens, stimulants, cannabinoids and hallucinogens.

Another likely factor to consider is the disproportionate societal stigma of opioids at present. With a disproportionate & irrational degree of emphasis by media on prescription "heroin substitutes" and the so-called "opioid epidemic", "dope" has again become public enemy number 1 in recent years. With federal law enforcement having launched a full scale witch hunt against doctors, dealers, distributors and even medical patients. Few commercial chemists would take such a risk.

The witch hunt which would likely ensue following a single overdose - or one bizarre criminal act in which the perpetrator incidentally happens to be under the influence of an opioid RC - could very well be a death knell to the young and delicate RC industry. This is really not a matter of which drug is more dangerous or harmful, but a matter of which drug-associated incident would draw more mindless handwringing & moral panic.

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